Octet

Octet / Reagents

Sodium Triacetoxyborohydride

Sodium Triacetoxyborohydride (NaBH(OAc)₃) - reducing reagent. Mild, selective reduction. Common uses: Reductive amination, Reduces iminium ions selectively. Safer than NaBH₃CN (no HCN). Very selective. Mild conditions.

Reducing

Reagent details

Name

Sodium Triacetoxyborohydride

Formula

NaBH(OAc)₃

Category

Reducing

Function

Mild, selective reduction

Common Uses

  1. Reductive amination

  2. Reduces iminium ions selectively

Notes

Safer than NaBH₃CN (no HCN). Very selective. Mild conditions.

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Reagents

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Dissolving Metal (Na/NH₃) (Na + NH₃(l)) - reducing reagent. Reduction of alkynes to trans-alkenes. Common uses: Alkyne → trans-Alkene. Birch reduction conditions. Liquid ammonia at -33°C. Radical mechanism gives trans product.

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