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Aldol Condensation

Aldol Condensation (Carbonyl.) Converts CC=O to CC=CC=O using NaOH, heat.

Carbonyl

Reaction details

Name

Aldol Condensation

Type

Carbonyl

Starting Material

CC=O

Product

CC=CC=O

Reagents
  • NaOH

  • heat

Mechanism
  1. Smiles

    CC=O

    Description

    Acetaldehyde

  2. Smiles

    CC(O)CC=O

    Description

    First: aldol addition

  3. Smiles

    CC=CC=O

    Description

    Heat causes dehydration → conjugated enone

Tips
  1. Condensation = addition + elimination of water

  2. Heat favors elimination (entropy)

  3. Product is α,β-unsaturated carbonyl

Related Reactions
  • aldol-addition

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