Octet

Octet / Functional Groups

Alkyl Halide

Alkyl Halide (R-X (X = F, Cl, Br, I)) - halides. Halogen on sp³ carbon. Undergo substitution (SN1/SN2) and elimination (E1/E2).

Halides

Functional Group details

Name

Alkyl Halide

Category

Halides

Smiles

CCBr

General Formula

R-X (X = F, Cl, Br, I)

Description

Halogen on sp³ carbon. Undergo substitution (SN1/SN2) and elimination (E1/E2).

Properties
Polarity

polar

H Bond Donor

No

H Bond Acceptor

No

Boiling Point Trend

Higher than alkanes (I > Br > Cl > F)

Spectroscopy
Ir Peaks
  1. 500-800 cm⁻¹ (C-X stretch)

H Nmr Shifts
  1. 3.0-4.0 ppm (α-H)

C Nmr Shifts
  1. 10-40 ppm (shifted by halogen)

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