Octet

Octet / Functional Groups

Primary Amine

Primary Amine (R-NH₂) - nitrogen. Nitrogen with two H atoms. Basic and nucleophilic. Fishy smell.

Nitrogen

Functional Group details

Name

Primary Amine

Category

Nitrogen

Smiles

CCN

General Formula

R-NH₂

Description

Nitrogen with two H atoms. Basic and nucleophilic. Fishy smell.

Properties
Polarity

polar

H Bond Donor

Yes

H Bond Acceptor

Yes

Boiling Point Trend

Higher than alkanes due to H-bonding

Spectroscopy
Ir Peaks
  1. 3300-3500 cm⁻¹ (N-H stretch, two peaks)

H Nmr Shifts
  1. 0.5-3.0 ppm (NH₂, broad, variable)

C Nmr Shifts
  1. 30-50 ppm (C-N)

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