Octet

Octet / Functional Groups

Secondary Amine

Secondary Amine (R-NH-R') - nitrogen. Nitrogen with one H atom. Basic and nucleophilic.

Nitrogen

Functional Group details

Name

Secondary Amine

Category

Nitrogen

Smiles

CCNCC

General Formula

R-NH-R'

Description

Nitrogen with one H atom. Basic and nucleophilic.

Properties
Polarity

polar

H Bond Donor

Yes

H Bond Acceptor

Yes

Boiling Point Trend

Slightly lower than 1° amines

Spectroscopy
Ir Peaks
  1. 3300-3500 cm⁻¹ (N-H stretch, one peak)

H Nmr Shifts
  1. 0.5-3.0 ppm (NH, broad)

C Nmr Shifts
  1. 40-60 ppm (C-N)

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