Octet

Octet / Functional Groups

Phenol

Phenol (Ar-OH) - aromatics. OH on benzene ring. More acidic than alcohols (pKa ~10). Activates ring for EAS.

Aromatics

Functional Group details

Name

Phenol

Category

Aromatics

Smiles

c1ccccc1O

General Formula

Ar-OH

Description

OH on benzene ring. More acidic than alcohols (pKa ~10). Activates ring for EAS.

Properties
Polarity

polar

H Bond Donor

Yes

H Bond Acceptor

Yes

Boiling Point Trend

High BP due to H-bonding

Spectroscopy
Ir Peaks
  1. 3200-3600 cm⁻¹ (O-H)

  2. 1200-1400 cm⁻¹ (C-O)

H Nmr Shifts
  1. 4-8 ppm (OH)

  2. 6.5-7.5 ppm (aromatic)

C Nmr Shifts
  1. 115-165 ppm

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