Octet

Octet / Functional Groups

Sulfide (Thioether)

Sulfide (Thioether) (R-S-R') - sulfur. Sulfur analog of ether. Better nucleophile than ethers. Can be oxidized to sulfoxides/sulfones.

Sulfur

Functional Group details

Name

Sulfide (Thioether)

Category

Sulfur

Smiles

CSC

General Formula

R-S-R'

Description

Sulfur analog of ether. Better nucleophile than ethers. Can be oxidized to sulfoxides/sulfones.

Properties
Polarity

slightly polar

H Bond Donor

No

H Bond Acceptor

Yes

Boiling Point Trend

Higher than ethers

Spectroscopy
Ir Peaks
  1. 600-700 cm⁻¹ (C-S stretch)

H Nmr Shifts
  1. 2.0-2.5 ppm (α-H)

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